Cytosine monohydrate
WebOct 1, 2008 · Single crystals of cytosine monohydrate with copper impurities were grown by slow evaporation of the aqueous solution, to which a small amount of copper nitrate was added. Partly deuterated crystals, in which hydrogen atoms bound to nitrogen and oxygen were replaced by deuterium, were grown from the heavy water solution in the same way. ... WebSingle crystals of cytosine monohydrate were irradiated with ..gamma.. rays at 77 K, and the electron spin resonance (ESR) spectra were recorded while gradually increasing the temperature. The analysis of the decrease in line intensity shows that the disappearance of cation and anion radicals is due predominantly to their mutual recombination.
Cytosine monohydrate
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WebOct 1, 1973 · In the irradiated single crystal of cytosine monohydrate the radical with g 1 = 2.036, g 2 = 2.009, and g 3 = 2.001 and a doublet structure has been attributed to the thiocytosine species. Concentration of the thio-cytosine molecules depends upon the commercial source of the substance. The observed sulfur radical has a π-electronic … WebDec 1, 1995 · Assuming an average theoretical value of kappa H = 1.24, the molecular dipole moments calculated from the monopole and dipole pseudoatom population parameters are 17 (4) and 8.2 (15) Debye for cytidine nucleoside and cytosine in the monohydrate, respectively. Systems of atomic point charges are presented for cytidine, …
WebJun 24, 2024 · Introduction Cytosine (C) is the fundamental genetic unit of the … WebApr 14, 2024 · 3/n 但事实上,对公链妖魔化的狭隘观念仅存于部分领导层,实际上各行业 …
WebCytosine and cytosine monohydrate are representative biomolecules for investigating the effect of hydrogen bonds in deoxyribonucleic acid. To better understand intermolecular interactions, such as hydrogen bonds, between nucleobases it is necessary to identify the low-frequency vibrational modes associated with intermolecular interactions and … WebNov 8, 2024 · Monohydrate and anhydrate crystalline forms of the DNA nucleobase cytosine interconvert via a topotactic solid-state mechanism where water functions as a molecular switch. The solid-state dehydration …
WebApr 1, 1999 · Single crystals of cytosine monohydrate were x-irradiated at 10 K and …
WebThe total free radical yield has been measured for crystals of five pyrimidine derivatives: thymine (T), 1-methylthymine (1MeT), 1-methyluracil (1MeU), 1-methylcytosine (1MeC) and cytosine monohydrate (C:HOH). Q-band EPR measurements were made on samples X-irradiated between 4 and 12 K. The G values … can\\u0027t shutdown iphoneWebApr 1, 1999 · Single crystals of cytosine monohydrate were x-irradiated at 10 K and examd. using K-band EPR, ENDOR, and FSE spectroscopy at temps. between 10 K and room temp. Three radicals dominated the low-temp. spectra. Radical RI is the cytosine anion protonated at the N3-position. A large coupling to HC6 and smaller couplings to … can\u0027t shut down pc windows 11WebFeb 2, 2024 · cytosine 5-hydrogen sulfate. 51392-11-1. Chemsrc provides cytosine … can\u0027t shutdown pc windows 10WebCytosinium 4-nitrobenzoate cytosine monohydrate C15H17N7O7 CID 139060525 - … bridgepoint pharr txWebThe distances and angles of the cytosine moiety of the molecule do not compare well with those found in cytosine monohydrate and cytidine. The discrepancies are attributed to the influence of hydrogen bonding on the double bond character of the carbonyl bond C*(2)-O*(2) and on the influence of the N 4 a axis which are held together by van der ... can\\u0027t shutdown laptopWebJan 1, 1983 · Neutron diffraction, thermogravimetric, and mass spectrographic measurements have been used to show that cytosine monohydrate loses its water of hydration at physiological temperatures (approximately equal … can\\u0027t shutdown remote desktop computercan\u0027t shutdown pc